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    • Thermodynamics >
      • Thermochemistry Worksheet + Answers
      • First Law of Thermodynamics
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      • Enthalpy
      • Hess' Law
      • Enthalpy of Formation
      • Heat Capacity
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      • Spontaneity at Different Temperatures
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      • Redox Reactions
      • Introduction to Half-Reactions
      • Calculating Oxidation Number
      • Has a Redox Reaction Occurred?
      • How to Balance Redox Reactions (Acidic Solution)
      • How to Balance Redox Reactions (Basic Solution)
      • Galvanic Cells
      • Standard Reduction Potentials
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      • Nernst Equation
    • Kinetics >
      • Introduction
      • Relative Rates of Reaction
      • Rate Laws
      • Zero-Order Reactions
      • First-Order Reactions
      • Second-Order Reactions
      • Half-Life Expressions
      • Arrhenius Equation
      • How Long will it Take to Decay?
      • What Order is this Reaction?
      • Find the Rate Constant
    • Gases >
      • Pressure, Volume, Temperature
      • Ideal Gas Law
      • Density of Gases
      • Ideal Gas Law and Changes in P, V, T
      • Kinetic Molecular Theory
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      • Partial Pressures
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      • Solve Titration Questions
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      • Ranking by Boiling/Melting Point
      • Clausius-Clapeyron Equation
      • Heating Curves
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      • Ionic/Metallic/Covalent
      • Symmetry of Solids
      • Simple Cubic, fcc and bcc
      • How to Find Edge Length
    • Organic Reactions >
      • Br2 + Alkene (Adding across a double bond)
      • HCl + Alkene (Adding across a double bond)
      • Reaction of OH with Alkyl Halide
      • What is Regioselectivity?
      • Stability of Carbocations
    • Moles and Mass >
      • Average Atomic Mass
      • Solve for Isotopic Abundance
      • Limiting Reagents
      • Percent Yield
      • Actual Yield and Percentage Yield
      • Percent Composition
    • Atomic Structure >
      • What's in an Atom?
      • Quantum Numbers
      • Pauli, Aufbau, Hund
      • Light: E h ν λ
      • Energy Levels of Hydrogen
      • Energy Levels of Non-Hydrogen Atoms
    • Organic Naming >
      • Naming Organic Molecules
      • How to Name Amines
      • How to Name Amides
    • Lewis Structures
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Limiting Reagents



If you're given information about the reactants in a chemical reaction, and need to find out something about the products, you'll likely have to figure out which reactant will run out first.  Chemists call the reactant that runs out first the limiting reagent and you need to be able to find it. It's easier than you might think ... just follow these steps!
Q: How much CO2 and H2O is formed (in g) when 3 g of CH4 react with 5 g of O2?
A: 

Step 1 - Create a balanced chemical equation
Picture
Step 2 - Calculate the number of moles of EACH reactant
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Step 3 - Figure out which reactant is limiting (will run out FIRST)

TRICK: Divide the number of moles of each by the coefficient in the balanced chemical formula. The substance that gives the smallest number this way is the limiting reagent.  This works because, in the example we're working on, O2 is consumed TWICE as fast as CH4 ... so we need double as much O2 as CH4 !
Picture
So, O2 is the limiting reagent.

Step 4 - Figure out how much of each product forms (which are you asked about?)

O2 is the limiting reagent, so we consume all 0.15625 mol of it.   This is our benchmark.  Multiply this number by the coefficient of the product you're solving for, and divide by the coefficient of the reactant that is limiting.  Alternatively, look at the last two calculations here...
Picture
Step 5 - Convert to whatever units you need

Often, this means converting them to "mass":
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