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  • Home / Ask Me Stuff
  • Free Lessons
    • Thermodynamics >
      • Thermochemistry Worksheet + Answers
      • First Law of Thermodynamics
      • Pressure-Volume Work
      • Enthalpy
      • Hess' Law
      • Enthalpy of Formation
      • Heat Capacity
      • Calorimetry
      • Entropy
      • Third Law of Thermodynamics
      • Spontaneity: Gibbs Free Energy
      • Second Law of Thermodynamics
      • Spontaneity at Different Temperatures
    • Electrochemistry >
      • Redox Reactions
      • Introduction to Half-Reactions
      • Calculating Oxidation Number
      • Has a Redox Reaction Occurred?
      • How to Balance Redox Reactions (Acidic Solution)
      • How to Balance Redox Reactions (Basic Solution)
      • Galvanic Cells
      • Standard Reduction Potentials
      • Electrolytic Cells
      • Nernst Equation
    • Kinetics >
      • Introduction
      • Relative Rates of Reaction
      • Rate Laws
      • Zero-Order Reactions
      • First-Order Reactions
      • Second-Order Reactions
      • Half-Life Expressions
      • Arrhenius Equation
      • How Long will it Take to Decay?
      • What Order is this Reaction?
      • Find the Rate Constant
    • Gases >
      • Pressure, Volume, Temperature
      • Ideal Gas Law
      • Density of Gases
      • Ideal Gas Law and Changes in P, V, T
      • Kinetic Molecular Theory
      • van der Waals' Equation for Non-Ideal Gases
      • Partial Pressures
      • Kinetic Energy and Temperature
    • Equilibrium >
      • Writing Equilibrium Expressions
      • Le Chatelier's Principle
    • Acids and Bases >
      • Acids and Bases Worksheet + Answers
      • Arrhenius vs Bronsted-Lowry vs Lewis Acids
      • Solve Titration Questions
    • Intermolecular Forces >
      • Phase Diagrams
      • Phase Changes
      • Intermolecular Forces
      • Effects of Intermolecular Forces
      • Ranking by Boiling/Melting Point
      • Clausius-Clapeyron Equation
      • Heating Curves
    • Solids >
      • Ionic/Metallic/Covalent
      • Symmetry of Solids
      • Simple Cubic, fcc and bcc
      • How to Find Edge Length
    • Organic Reactions >
      • Br2 + Alkene (Adding across a double bond)
      • HCl + Alkene (Adding across a double bond)
      • Reaction of OH with Alkyl Halide
      • What is Regioselectivity?
      • Stability of Carbocations
    • Moles and Mass >
      • Average Atomic Mass
      • Solve for Isotopic Abundance
      • Limiting Reagents
      • Percent Yield
      • Actual Yield and Percentage Yield
      • Percent Composition
    • Atomic Structure >
      • What's in an Atom?
      • Quantum Numbers
      • Pauli, Aufbau, Hund
      • Light: E h ν λ
      • Energy Levels of Hydrogen
      • Energy Levels of Non-Hydrogen Atoms
    • Organic Naming >
      • Naming Organic Molecules
      • How to Name Amines
      • How to Name Amides
    • Lewis Structures
  • Privacy Policy
  • Free Help on Discord

First Law of Thermodynamics


First Law of Thermodynamics: In any system, the total energy of the system and the surroundings is constant.

Translation: Energy is not created or destroyed in chemical reactions ... only interconverted between different forms, like kinetic energy (temperature) and potential energy (bond energy).

If a system is isolated, the total energy inside the system always remains constant.

The only way to change the total energy of the system is for the surroundings to cause it ... either by adding/removing heat (Δq) or by performing work on the system, such as an expansion or compression) (ΔW).
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