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  • Home / Ask Me Stuff
  • Free Lessons
    • Thermodynamics >
      • Thermochemistry Worksheet + Answers
      • First Law of Thermodynamics
      • Pressure-Volume Work
      • Enthalpy
      • Hess' Law
      • Enthalpy of Formation
      • Heat Capacity
      • Calorimetry
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      • Third Law of Thermodynamics
      • Spontaneity: Gibbs Free Energy
      • Second Law of Thermodynamics
      • Spontaneity at Different Temperatures
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      • Redox Reactions
      • Introduction to Half-Reactions
      • Calculating Oxidation Number
      • Has a Redox Reaction Occurred?
      • How to Balance Redox Reactions (Acidic Solution)
      • How to Balance Redox Reactions (Basic Solution)
      • Galvanic Cells
      • Standard Reduction Potentials
      • Electrolytic Cells
      • Nernst Equation
    • Kinetics >
      • Introduction
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      • Zero-Order Reactions
      • First-Order Reactions
      • Second-Order Reactions
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      • Arrhenius Equation
      • How Long will it Take to Decay?
      • What Order is this Reaction?
      • Find the Rate Constant
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      • Pressure, Volume, Temperature
      • Ideal Gas Law
      • Density of Gases
      • Ideal Gas Law and Changes in P, V, T
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      • Partial Pressures
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      • Writing Equilibrium Expressions
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      • Acids and Bases Worksheet + Answers
      • Arrhenius vs Bronsted-Lowry vs Lewis Acids
      • Solve Titration Questions
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      • Phase Diagrams
      • Phase Changes
      • Intermolecular Forces
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      • Ranking by Boiling/Melting Point
      • Clausius-Clapeyron Equation
      • Heating Curves
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      • Ionic/Metallic/Covalent
      • Symmetry of Solids
      • Simple Cubic, fcc and bcc
      • How to Find Edge Length
    • Organic Reactions >
      • Br2 + Alkene (Adding across a double bond)
      • HCl + Alkene (Adding across a double bond)
      • Reaction of OH with Alkyl Halide
      • What is Regioselectivity?
      • Stability of Carbocations
    • Moles and Mass >
      • Average Atomic Mass
      • Solve for Isotopic Abundance
      • Limiting Reagents
      • Percent Yield
      • Actual Yield and Percentage Yield
      • Percent Composition
    • Atomic Structure >
      • What's in an Atom?
      • Quantum Numbers
      • Pauli, Aufbau, Hund
      • Light: E h ν λ
      • Energy Levels of Hydrogen
      • Energy Levels of Non-Hydrogen Atoms
    • Organic Naming >
      • Naming Organic Molecules
      • How to Name Amines
      • How to Name Amides
    • Lewis Structures
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Energy Levels of Non-Hydrogen Atoms


Just like for hydrogen, there is a formula for calculating the energy of electron transitions for ANY atom that only has one electron.  This kind of thing happens more often on tests than in the real world.  Example of atoms that this applies to are:
Picture
Since each of these atoms can only have one electron, each atom needs a progressively larger positive charge.  Very quickly, the charges get ridiculously large.

Nonetheless, there are formulas to predict the energy and wavelength of electron transitions in these types of atoms:
Picture
Picture
Z is the atomic number of the atom (so it's 2 for Helium, 3 for Lithium, or 6 for Carbon).  That's right.  They're exactly the same as for hydrogen, except with an extra Z^2 term. In fact, hydrogen follows this formula too, but since Z=1 we just simplify the formula.

Sample Question

Q: How much energy is RELEASED when an electron falls from n=6 to n=2 in a B(4+) atom?  What wavelength is a photon with that amount of energy?

A: Notice how I used the same question as from the "Energy Levels of Hydrogen" page, but changed it to a B(4+) atom?  This is solved the exact same way, just don't forget the Z^2!

E = 1.893 x 10^-18 J
wavelength = 1.05 x 10^-7 m = 105 nm
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